Electron paramagnetic resonance investigation of molecular bond rupture due to ozone in deformed rubber

Electron paramagnetic resonance (EPR) provides a sensitive tool by which microscopic bond rupture can be monitored simultaneously with observations of macroscopic deformation and failure. Past techniques for studying fracture in semicrystalline polymers have been extended to investigate degradation of unfilled ruber in the presence of ozone. It was found that the rate of free radical production was linearly proportional to stretch ratio and ozone concentration and that stress relaxation and creep were not directly proportional to this production rate. The latter behavior was attributed to the particular dependence of crack density and growth on stress. It was concluded that at low strains, comparatively few surface cracks form; however, at higher strains, many more crack centers become active. Although many more surface cracks are present, they do not progress into the material as rapidly. Therefore, although more bonds were broken at higher strains and stresses, the stress relaxation rate and creep rates were not significantly increased.     

Self-Assembled Microfibers of Simple Amphiphilic Molecules Through a Facile Precipitation Route

One-dimensional (1D) fiber structures of simple amphiphilic molecules were prepared through a facile precipitation route. The self-assembly process was studied by ultraviolet-visible absorption and Fourier transform infrared) spectroscopy, which indicated that hydrogen bonding interactions played a role in the1D growth along the axis of the fiber. The water content, self-assembling temperature, and concentration of 1,5-bis-(1-(pyridin-2-yl)ethylidene)thiocarbonohydrazide molecules in the solution had obvious effects on the size and morphology of the self-assembled products. The formation of1D superstructures is not only of a hot subject in the process of nanoscience but also opens a new venue for conveniently controlling self-assembled structures of similar organic molecules.     

基于法布里-珀罗调谐滤波器的傅里叶域锁模扫频激光光源

报道了一个光纤型1300 nm波段的傅里叶域锁模(Fourier domain mode locking, FDML)扫频激光光源, 用于扫频光学相干层析成像技术 (optical coherence tomography, OCT) 成像. 本实验扫频激光光源采用包含增益介质、调谐滤波器和延迟线组成的长腔激光谐振腔以及光功率增强单元. FDML扫频激光光源具有快速和高度稳定运转模式, 相位稳定性好. 基于法布里-珀罗调谐滤波器(fiber Fabry-Perot tunable filter, FFP-TF)的FDML扫频激光光源扫频范围为130 nm, 半高全宽为70 nm, 输出平均功率是11 mW. 与基于FFP-TF的短腔的扫频光源做了对比研究, FDML扫频光源速度从短腔的8 kHz提高到了48.12 kHz, 对应生物组织OCT成像轴向分辨率为7.8 μm, 比短腔的减小了1.9 μm. 关键词： 光学相干层析技术 扫频激光光源 傅里叶域锁模 法布里-珀罗调谐滤波器     

微机械框架陀螺仪的动力学分析

本文根据欧拉动力学方程导出微机械框架陀螺仪的动力学方程，给出陀螺仪的运动规律，并探讨惯性质量对测量灵敏度的影响。     

The Ideal Completion of a Noetherian Local Domain

The ideal topology on a integral domain R is the linear topology which has as a fundamental system of neighborhoods of 0 the nonzero ideals of R. We investigate the properties of the ideal topology on a Noetherian local domain (R, 𝔪), and we establish connections between the 𝔪-adic completion and the ideal completion. We give conditions under which the completion in the ideal topology is Noetherian, and we show that, unlike the 𝔪-adic completion, the completion in the ideal topology is not always Noetherian.     

基于飞秒激光直写光纤光栅的掺镱光纤激光器

 利用飞秒激光微加工技术,可以在光纤纤芯内直写出布拉格光栅,它与传统的光纤光栅制作方法相比,具有耗时短、无需光敏光纤、周期可任意设定、光栅稳定性高等优点。采用800 nm钛宝石飞秒激光器,在Hi1060光纤内写入一支8 mm长的布拉格光栅,光纤光栅的周期为2.9 μm,这是中心波长为1 042 nm的八阶光纤布拉格光栅。将所得光栅与一段有源的双包层光纤熔接,作为激光输出镜,利用975 nm的LD光纤模块作为泵浦源,采用端泵浦技术构成双包层光纤激光器。双包层光纤采用Nufern公司镱(Yb³⁺)离子掺杂双包层光纤,光纤长度3 m。所得激光器的输出功率为71.1 W,中心波长1 042 nm,带宽约为0.8 nm。     

阵列波导光栅解调系统光电集成中Si纳米线AWG的设计

设计了一种阵列波导光栅解调集成系统中的8通道Si纳米线阵列波导光栅波分复用器。根据材料的折射率设计了单模波导截面尺寸,利用光束传播法对所设计阵列波导光栅进行了模拟。结果表明,器件尺寸为200μm×219μm,远小于目前技术较成熟的硅基SiO2的尺寸,光功率分布符合高斯分布,信道间隔为1.8nm,串扰小于-21dB。对小尺寸AWG的设计具有参考意义。     

梯度磁场作用下光纤中磁流体光透射特性研究的建模与分析

对光纤中磁流体在梯度磁场作用下的光透射特性进行了研究,提出光纤中磁流体的光透射率变化主要来源于梯度磁场引起的磁流体密度分布变化。根据郎之万函数和流体理论,推导了光纤中磁流体在梯度磁场作用下的密度分布,并根据Beer-Lambert定律,得到磁流体光功率透射衰减和纳米粒子局部密度的关系,从而建立光纤中磁流体在梯度磁场作用下光透射特性的理论模型。进而对光纤中磁流体在不同梯度磁场作用下的光透射功率进行数值分析,得到不同磁场强度和磁场梯度下光纤中磁流体透射功率的变化规律。最后将数值分析的结果和实验数据进行对比,验证了模型的合理性, 同时也验证了梯度磁场作用下磁流体光透射功率的变化主要来源于磁流体密度分布变化的推论。     

原油含水率测量的光学计量仪

油井含水率是油田开发过程中的一个重要指标。光纤传感器具有体积小、重量轻、抗干扰能力强、实时、高效、准确等优点,将其应用于石油测井,有利于提高勘探效率。介绍测井应用中原油含水率计量仪的结构,分析了光纤传感器对混合液体含水率测量的基本原理。激光在弯曲光纤中的传输效率随外界混合介质折射率的变化而改变,根据光纤输出光功率的大小可以测量外界混合介质的组成成分。通过数值模拟,给出了光纤传感器中光束强度随混合液体含水率的变化现象,计算得到混合液体中含水率测量结果。结果表明,光纤传感器计量仪能实现0%～100%含水量的连续测量。最后基于数值模拟结果讨论了系统设计中的注意事项。     

基于CDMA的布拉格光纤光栅传感系统的仿真分析

讨论了光纤光栅传感系统中常用的复用技术及其限制,阐述了利用CDMA技术实现光纤布拉格光栅阵列波长解调的复用方式,对系统的原理和性能进行了理论分析。在此基础上通过MATLAB做了基于CDMA的光纤光栅传感仿真分析,仿真结果表明该方法能区分反射波长重叠的光栅,从而提高FBG网络复用的频带利用率。